One-Pot Synthesis of Fatty Amines: Rh-Catalyzed Hydroaminomethylation of 1-Decene in an Aqueous Microemulsion System—Influence of Reaction Conditions on the Reaction Performance
نویسندگان
چکیده
The hydroaminomethylation of the long-chain olefin 1-decene and diethylamine with a homogeneous Rh(acac)(cod)/SulfoXantphos catalyst complex as one-pot synthesis was investigated. influence reaction conditions such temperature gas pressure determined, well effects initial concentrations precursor, ligand, reactants on yield fatty amine. Hydroaminomethylation successfully carried out in an aqueous microemulsion system using non-ionic surfactant time 2 h. A maximum 34%, high regioselectivities >97%, chemoselectivities >85% were achieved.
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ژورنال
عنوان ژورنال: Catalysts
سال: 2022
ISSN: ['2073-4344']
DOI: https://doi.org/10.3390/catal12070773